Whitley, J. W., Jeffrey Horne, W., Shannon, M. S., Andrews, M. A., Terrell, K. L., Hayward, S. S., Yue, S., Mittenthal, M. S., O’Harra, K. E., & Bara, J. E. (2018). Systematic Investigation of the Photopolymerization of Imidazolium-Based Ionic Liquid Styrene and Vinyl Monomers. Journal of Polymer Science Part A: Polymer Chemistry, 56, 2364–2375.
@article{2018-whitley-il-polymerization,
author = {Whitley, John W and Jeffrey Horne, William and Shannon, Matthew S and Andrews, Mary A and Terrell, Kelsey L and Hayward, Spenser S and Yue, Shuwen and Mittenthal, Max S and O'Harra, Kathryn E and Bara, Jason E},
journal = {Journal of Polymer Science Part A: Polymer Chemistry},
numer = {20},
pages = {2364--2375},
publisher = {Wiley Online Library},
title = {Systematic Investigation of the Photopolymerization of Imidazolium-Based Ionic Liquid Styrene and Vinyl Monomers},
volume = {56},
year = {2018},
month = sep,
date = {2018-09-09},
doi = {10.1002/pola.29211}
}
The use of ionic liquids (ILs) as media in radical polymerizations has demonstrated the ability of these unique solvents to improve both reaction kinetics and polymer product properties. However, the bulk of these studies have examined the polymerization behavior of common organic monomers (e.g., methyl methacrylate, styrene) dissolved in conventional ILs. There is increasing interest in polymerized ILs (poly(ILs)), which are ionomers produced from the direct polymerization of styrene-, vinyl-, and acrylate-functionalized ILs. Here, the photopolymerization kinetics of IL monomers are investigated for systems in which styrene or vinyl functionalities are pendant from the imidazolium cation. Styrene-functionalized IL monomers typically polymerized rapidly (full conversion ≤1 min) in both neat compositions or when diluted with a nonpolymerizable IL, [C2mim][Tf2N]. However, monomer conversion in vinyl-functionalized IL monomers is much more dependent on the nature of the nonpolymerizable group. ATR-FTIR analysis and molecular simulations of these monomers and monomer mixtures identified the presence of multiple intermolecular interactions (e.g., π–π stacking, IL aggregation) that contribute to the polymerization behaviors of these systems.